Add-ons can alert you based on aura gain/loss , however they can not perform actions for you.
Using your own example:
Add-on will be able to check what debuff player gets; you can make a list of such debuffs that are breakable with freedom and the add-on will check if the debuff you got is on that list; and finally it can warn you in any shape or form... e.g. screen turning red, shaking, flying ponies, dancing strippers etc..
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