nUI automatically integrates with Clique if you have it installed. If you have a spell attached to the right click then that's what's going to happen. Generally, left click is assigned to targeting, right click to the menu and everything else to whatever makes you happy.
If you have told Clique to replace the right-click menu feature with a spell, then that's kind of what you're stuck with. It might be possible, however, have Clique assign some other click sequence to the menu.
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