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I don't think the proc visual can be moved as it is a new feature to wow in general and nUI 5 never had it to customise with.
Moving the cast bar can be done using the Layout lua files relevant to the HUD layout you want to use/change. Bear in mind though that moving one element of the hud could affect others as some items are anchored together.
This thread deals with a similar problem and may help you with tweaking the positioning.
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