Okay -- If you're only seeing player, party and 10 man raid frames, then you are running the release version of nUI. The 15, 20, 25 and 40 man frames are still in the development line and have not been officially released.
As for seeing your debuffs, there are two ways... the easiest is to enable the HUD. It has a bar in the lower center that contains only the auras you have cast on the current target and their time remaining. If you don't like having the health bars in the HUD, then select the "Simple HUD" mode and you'll only get the DOT/HOT bar, cooldown bar, casting bar and health race bar. You have the option to turn the health race and cooldown bars off via slash commands, as well (though I strongly recommend against it).
And yes, the GUI setup is something that has been discussed at great length. It's also in the patch notes and to-do list. It's a HUGE undertaking and going to take time... everything nUI is configurable, so that's a lot of GUI config to write.
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