As there really isn't a way to track someone as a RealID friend, no. Even if there was, there is no API to scan their alts. You would have to have an addon catch every char they log in on and build its own list.
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WoWInterface AddOns
"All I want is a pretty girl, a decent meal, and the right to shoot lightning at fools."
-Anders (Dragon Age: Origins - Awakening)
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