Now that I have slept -
When you install into Program Files (or Program files (x86)) in Vista or 7, it requires Admin privileges to write to that folder. This is fine - you don't need to write your WTF folder there.
Vista and 7 both use a virtualization system that says, "Okay, no admin privilege, and I have to write to a protected area - so it's being redirected to another folder". You can only write to these protected folders if you turn virutalization off for that program AND give your useraccount write-access to the folder.
This is the one that ShetiPhan mentioned - C:\Users\<username>\AppData\Local\VirtualStore\ - and then in subfolders from there. It'd look like WoW or World of Warcraft\WTF\ and the usual mess, I believe.
So all of the WTF and other folders are actually there when you don't run as Admin.
I get around this by keeping WoW installed in an area that's not protected under virtualization - C:\WoW, for example.
Folders protected under Virtualization are Program Files, Program Files (x86), and the main Windows folder - and their subfolders, of course.
EDIT:
Oh, and when you moved it to your Documents folder - it ignored virtualization, and wrote in the default folder, because "Documents" is in C:\Users, which isn't protected.
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-- Taryble
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